Tetrakis(triphenylphosphine)palladium (0)

Description

T4677H   Tetrakis(triphenylphosphine)palladium (0)
[ 14221-01-3 ]   f.w.: 1155.57
  • Catalyst for Suzuki coupling of chiral secondary organoboronic esters
  • Palladium-catalyzed SNAr reactions for the synthesis of heteroaryl ethers
  • Catalyst for cross-coupling of a-diazocarbonyl compounds with arylboronic acids
  • Diasteroselective synthesis of trans-1,2-daizetidines
  • Palladium-catalyzed alkynyl iminium ion cyclozation
  • Widely used reagent in a variety of transformations including Heck arylation, enyne and diyne cycloisomerization
  • Catalyst for cross-coupling
  1. J. Am. Chem. Soc., 2009, 131, 5024.
  2. J. Am. Chem. Soc., 2009, 131, 4174.
  3. J. Am. Chem. Soc., 2008, 130, 1566.
  4. Angew. Chem. Int. Ed., 2008, 47, 4581.
  5. Angew. Chem. Int. Ed., 2008, 47, 4851.
  6. Acc. Chem Res., 1990, 23, 34.
  7. Angew. Chem. Int. Ed., 1995, 34, 1721.
  8. Pure Appl. Chem., 1994, 66, 1471.
  9. J. Am. Chem. Soc., 1984, 106, 7500.
  10. Encyclopedia of Reagents for Organic Synthesis, 1995, Vol. 7, 4786.
  11. Comprehensive Organic Synthesis. 1991, Vol. 3, Chapter 2.4, 521.
  12. Palladium Reagents in Organic Synthesis, 1995, Chapter 6.
  13. Handbook of Organopalladium Chemistry for Organic Synthesis, 1st Ed., John Wiley & Sons, 2002 (review)

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